MCAT General Chemistry Review
Chapter 11: Oxidation–Reduction Reactions
Answers and Explanations
1. CThe oxidizing agent is the species that is reduced in any given equation. In this problem, six hydrogen atoms with +1 oxidation states in NH3 are reduced to three neutral H2 molecules.
First, balance the atoms in the equation:
Cr2O72− + 14 H+ → 2 Cr2+ + 7 H2O
Now, adjust the number of electrons to balance the charge. Currently, the left side has a charge of +12 (–2 from dichromate and +14 from protons). The right side has a charge of +4 (+2 from each chromium cation). To decrease the charge on the left side from +12 to +4, we should add 8 electrons:
Cr2O72− + 14 H+ + 8 e− → 2 Cr2+ + 7 H2O
3. AHydride ions are composed of a hydrogen nucleus with two electrons, thereby giving it a negative charge and a considerable tendency to donate electrons. LiAlH4 is therefore a strong reducing agent. Strong reducing agents tend to have metals or hydrides; strong oxidizing agents tend to have oxygen or a similarly electronegative element.
4. CIn NaClO (sodium hypochlorite), sodium carries its typical +1 charge, and oxygen carries its typical –2 charge. This means that the chlorine atom must carry a +1 charge in order to balance the overall charge of zero.
5. DA strong oxidizing agent will be easily reduced, meaning that it will have a tendency to gain electrons. Atoms usually gain electrons if they are one or two electrons away from filling up their valence shell. Choice (A) has a full 4s-orbital, meaning that it can only gain an electron if it gains an entire p subshell. Choice (B) has a stable, half-full 3d-orbital, so it is unlikely to pick up electrons unless it can gain five. Choice (C) has only a single electron in the outer shell, which is more likely lost upon ionization. Choice (D) would fill up its 4p-orbital by gaining one electron, so it is easily reduced.
6. DA net ionic equation represents each of the aqueous ions comprising the reactants and products as individual ions, instead of combining them as formula units. Thus, Choice (A) is not a net ionic reaction. The term net means that the correct answer does not include any spectator ions (ions that do not participate in the reaction). In this reaction, nitrate (NO3−) remains unchanged. Therefore, choices (B) and (C) are eliminated.
What you are shown is a net ionic equation. If two moles of FeSCN are created, two moles of Fe3+ must be used because the mole ratio is 1:1. Read the question stem carefully—we are asked for the mass of iron sulfate that is necessary, not the amount of iron, which would be 111.6 g, choice (A). Iron sulfate has the formula Fe2(SO4)3 because sulfate has a charge of –2 and iron has a charge of +3 (based on the net ionic equation). Therefore, one mole of iron sulfate is needed to make two moles of iron for the reaction. The molar mass of iron sulfate is
8. DWhen assigning oxidation numbers, one starts with elements of known oxidation state first, and determines the oxidation state of the other elements by deduction. As a noble gas, argon, choice (A), will always have an oxidation state of 0. As a group VIIA element, fluorine, choice (B), will have an oxidation state of 0 (by itself) or –1 (in a compound). As a group IIA element, strontium, choice (C), will have an oxidation state of 0 (by itself) or +2 (in a compound). Like most transition metals, iridium, choice (D), can have various oxidation states, ranging from –3 to +8. Therefore, one would have to determine the oxidation states of other atoms in an iridium-containing compound to determine iridium’s oxidation number.
The formula for methanol is H3COH, for methanal is H2CHO, and for methanoic acid is HCOOH. If we assign oxidation numbers to carbon in each molecule, it starts at –2, then becomes 0, then becomes +2:
In general, it is often easier to think of oxidation as a gain of bonds to oxygen (or a similarly electronegative element) or loss of bonds to hydrogen for organic compounds. Therefore, because the carbon is oxidized as one converts from an alcohol to an aldehyde to a carboxylic acid, the oxidation number must increase.
10.CStart with the atoms that have oxidation states of which you are certain. Potassium is a Group IA metal, and therefore must have an oxidation state of +1. Hydrogen is almost always +1, unless it is paired with a less electronegative element (which is not the case here). Oxygen is generally –2. Because there are four oxygens, they create a total negative charge of –8 which is partially balanced by two hydrogens (+2) and potassium (+1). Therefore, phosphorus has a +5 charge, making it the highest oxidation state.
11.BRecall that oxygen has an oxidation state of –2. Therefore, in tungsten(IV) oxide, choice (A), tungsten has an oxidation state of +4. In tungsten(VI) oxide, choice (B), it has an oxidation state of +6. In tungsten(III) oxide, choice (C), it is +3. In tungsten pentoxide, choice (D), it is +5.
12.AStep I is a disproportionation reaction because chlorine starts with an oxidation state of 0 in the reactants and ends up with an oxidation state of +1 in HOCl and –1 as Cl–. In the other reactions, no element appears with different oxidation states in two different products. Therefore, only step I is a disproportionation reaction.
13.CPotentiometry refers to carrying out an oxidation–reduction titration with a voltmeter present to get precise readings of the reaction’s electromotive force (emf) to determine the endpoint. This is analogous to using a pH meter in an acid–base titration because it uses technology to get precise readings for plotting a titration curve. Indicators, as in choices (A) and (B), can be used in both acid–base and redox titrations, but provide a qualitative (rather than quantitative) analysis of the titration. Oxidizing and reducing agents are used in redox titrations, not acid–base titrations, eliminating choice (D).
Utilize the method described earlier to balance this redox reaction. The balanced half-reactions are:
To get equal numbers of electrons in each half-reaction, the oxidation half-reaction will have to be multiplied by 3, and the reduction half-reaction will have to be multiplied by 32:
This makes the overall reaction:
3S8 + 32 NO3− + 8 H2O → 24 SO32− + 32 NO + 16 H+
The sum of the stoichiometric coefficients is therefore 3 +32 + 8 + 24 + 32 + 16 = 115.
First, balance the chemical equation:
4 Au + 8 NaCN + O2 + 2 H2O → 4 Na[Au(CN)2] + 4 NaOH
Now, determine the number of moles of NaCN used in the reaction:
If 0.2 mol NaCN are used in the reaction, then 0.2 mol