Process Technology: An Introduction - Haan A.B. 2015
8 Absorption and stripping
8.2 The aim of absorption
Generally the commercial purpose of absorption processes can be divided into gas purification or product recovery, depending on whether the absorbed or the unabsorbed portion of the feed gas has the greater value. Typical gas purification applications are listed in Tab. 8.1. The removal CO2 from synthesis gas in ammonia production and the removal of acid gases (CO2 H2S) from natural gas are some of the most widespread applications which are being improved continuously by the development of new solvents, process configurations and design techniques. In both applications stripping is used for absorbent regeneration.
Examples of absorption processes for product recovery are listed in Tab. 8.2. The absorption of SO3 and NOx in water to make concentrated sulfuric respectively nitric acid are probably the most widely-used product recovery applications of absorption. Other frequently encountered examples are the recovery of various products from a gaseous product stream by inert absorbents such as water. In some cases the absorber is used as a reactor where the desired chemical compound is obtained by a liquid phase reaction of the absorbed gases. An illustration of such a process is the production of urea from CO2 and ammonia.
Tab. 8.1: Typical applications of absorption for gas purification.
Impurity |
Process |
Absorbent |
Ammonia |
Indirect process (coke oven gas) |
Water |
Carbon dioxide and hydrogen sulfide |
Ethanolamine |
Mono— or di-ethanolamine in water |
Benfield |
Potassium carbonate and activatorin water |
|
Selexol |
Polyethylene glycol dimethyl ether |
|
Carbon monoxide |
Copper ammonium salt |
Cuprous ammonium carbonate and formate in water |
Hydrogen chloride |
Water wash |
Water |
Toluene |
Toluene scrubber |
Toluene |
Cyclohexane |
Scrubber |
Cyclohexane |
Tab. 8.2: Typical applications of absorption for product recovery.
Product |
Process |
Absorbent |
Acetylene |
Steam cracking of hydrocarbons (naphtha) |
Dimethylformamide |
Acrylonitrile |
Ammoxidation of propylene |
Water |
Maleic anhydride |
Butane oxidation |
Water |
Melamine |
Urea decomposition |
Water |
Nitric acid |
Ammonia oxidation (NOx absorption) |
Water |
Sulfuric acid |
Contact process (SO3 absorption) |
Water |
Urea |
Synthesis (CO2 and NH3 absorption) |
Ammonium carbamate solution |