Process Technology: An Introduction - Haan A.B. 2015

8 Absorption and stripping
8.2 The aim of absorption

Generally the commercial purpose of absorption processes can be divided into gas purification or product recovery, depending on whether the absorbed or the unabsorbed portion of the feed gas has the greater value. Typical gas purification applications are listed in Tab. 8.1. The removal CO2 from synthesis gas in ammonia production and the removal of acid gases (CO2 H2S) from natural gas are some of the most widespread applications which are being improved continuously by the development of new solvents, process configurations and design techniques. In both applications stripping is used for absorbent regeneration.

Examples of absorption processes for product recovery are listed in Tab. 8.2. The absorption of SO3 and NOx in water to make concentrated sulfuric respectively nitric acid are probably the most widely-used product recovery applications of absorption. Other frequently encountered examples are the recovery of various products from a gaseous product stream by inert absorbents such as water. In some cases the absorber is used as a reactor where the desired chemical compound is obtained by a liquid phase reaction of the absorbed gases. An illustration of such a process is the production of urea from CO2 and ammonia.

Tab. 8.1: Typical applications of absorption for gas purification.

Impurity

Process

Absorbent

Ammonia

Indirect process (coke oven gas)

Water

Carbon dioxide and hydrogen sulfide

Ethanolamine

Mono— or di-ethanolamine in water

Benfield

Potassium carbonate and activatorin water

Selexol

Polyethylene glycol dimethyl ether

Carbon monoxide

Copper ammonium salt

Cuprous ammonium carbonate and formate in water

Hydrogen chloride

Water wash

Water

Toluene

Toluene scrubber

Toluene

Cyclohexane

Scrubber

Cyclohexane

Tab. 8.2: Typical applications of absorption for product recovery.

Product

Process

Absorbent

Acetylene

Steam cracking of hydrocarbons (naphtha)

Dimethylformamide

Acrylonitrile

Ammoxidation of propylene

Water

Maleic anhydride

Butane oxidation

Water

Melamine

Urea decomposition

Water

Nitric acid

Ammonia oxidation (NOx absorption)

Water

Sulfuric acid

Contact process (SO3 absorption)

Water

Urea

Synthesis (CO2 and NH3 absorption)

Ammonium carbamate solution